Like cornstarch tapioca is a “pure starch” which means that compared to wheat flour it has no protein, bran or germ in it and as such packs more of a thickening punch. Tapioca comes in “pearls”, in granules (pieces of pearls) and in flour form. All can be used as thickeners, though the smaller the pieces the more readily they dissolve and the faster they act. Tapioca flour, my preference, dissolves almost instantaneously and because it gels at a lower temperature than cornstarch you can see the results immediately if the mixture is above 140 or so degrees Fahrenheit. Like other starch gels, however it also “un-thickens” when overcooked.